全文获取类型
收费全文 | 27633篇 |
免费 | 4837篇 |
国内免费 | 3933篇 |
专业分类
化学 | 20643篇 |
晶体学 | 317篇 |
力学 | 1539篇 |
综合类 | 226篇 |
数学 | 3855篇 |
物理学 | 9823篇 |
出版年
2024年 | 19篇 |
2023年 | 479篇 |
2022年 | 560篇 |
2021年 | 779篇 |
2020年 | 1074篇 |
2019年 | 1098篇 |
2018年 | 940篇 |
2017年 | 926篇 |
2016年 | 1355篇 |
2015年 | 1374篇 |
2014年 | 1606篇 |
2013年 | 2137篇 |
2012年 | 2516篇 |
2011年 | 2610篇 |
2010年 | 1871篇 |
2009年 | 1761篇 |
2008年 | 1995篇 |
2007年 | 1742篇 |
2006年 | 1551篇 |
2005年 | 1431篇 |
2004年 | 1187篇 |
2003年 | 947篇 |
2002年 | 1029篇 |
2001年 | 861篇 |
2000年 | 656篇 |
1999年 | 576篇 |
1998年 | 470篇 |
1997年 | 419篇 |
1996年 | 400篇 |
1995年 | 361篇 |
1994年 | 312篇 |
1993年 | 215篇 |
1992年 | 214篇 |
1991年 | 202篇 |
1990年 | 167篇 |
1989年 | 120篇 |
1988年 | 87篇 |
1987年 | 71篇 |
1986年 | 87篇 |
1985年 | 61篇 |
1984年 | 37篇 |
1983年 | 33篇 |
1982年 | 19篇 |
1981年 | 14篇 |
1980年 | 6篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1957年 | 4篇 |
1936年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
71.
72.
Vitamin K1 distribution following intravenous vitamin K1–fat emulsion administration in rats 下载免费PDF全文
Xue Xiao Yan‐Ni Mi Fa Wang Bing‐Hua Zhang Lei Cao Yong‐Xiao Cao 《Biomedical chromatography : BMC》2015,29(12):1849-1858
This study investigated vitamin K1 (VK1) distribution following intravenous vitamin K1–fat emulsion (VK1–FE) administration and compared it with that after VK1 injection. Rats were intravenously injected with VK1–FE or VK1. The organ and tissue VK1 concentrations were determined using high‐performance liquid chromatography method at 0.5, 2 and 4 h to determine distribution, equilibrium and elimination phases, respectively. In the VK1–FE group, the plasma, heart and spleen VK1 concentrations decreased over time. However, other organs like liver, lung, kidney, muscle and testis, reached peak VK1 concentrations at 2 h. In the VK1 injection group, the liver VK1 concentrations were significantly higher than those in other organs at the three time points. However, VK1 concentrations in the other organs peaked at 2 h. In addition, in VK1–FE group, the heart, spleen and lung VK1 concentrations were significantly higher than those in the VK1 injection group at the three time points, and the liver VK1 concentration was significantly higher than that in the VK1 injection group at 4 h. The VK1 amount was greatest in the liver compared with the other organs. Thus, the liver is the primary organ for VK1 distribution. The distribution of VK1 is more rapid when injected as VK1–FE than as VK1. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
73.
74.
Back Cover: Understanding the Origins of Nucleophilic Hydride Reactivity of a Sodium Hydride–Iodide Composite (Chem. Eur. J. 21/2016) 下载免费PDF全文
75.
Ag nanoparticle (NP)‐decorated MIL‐125(Ti) microspheres (Ag@MIL‐125(Ti)) were firstly fabricated via a facile hydrothermal and following photo‐reduction method. The photocatalysts were characterized using X‐ray diffraction, scanning and transmission electron microscopies, X‐ray photoelectron spectroscopy and UV–visible diffuse reflectance spectroscopy. The characterization results indicated that Ag NPs were dispersed on the surface of MIL‐125(Ti) microspheres, and the Ag NPs had a uniform diameter of about 40 nm. The composites exhibited excellent visible‐light absorption, due to the modification with the Ag NPs. The photocatalytic activity for the visible‐light‐promoted degradation of Rhodamine B was improved through the optimization of the amount of Ag loaded as a co‐catalyst, this amount being determined as 3 wt%. Additionally, studies performed using radical scavengers indicated that O2? and e? served as the main reactive species. The catalyst can be reused at least five times without significant loss of its catalytic activity. Furthermore, a photocatalytic mechanism for degradation of organics over Ag@MIL‐125(Ti) is also proposed. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
76.
Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface. 相似文献
77.
In this study, we present a method to predict the droplet ejection in thermal inkjet printheads including the growth and collapse of a vapor bubble and refill of the firing chamber. The three‐dimensional Navier–Stokes equations are solved using a finite‐volume approach with a fixed Cartesian mesh. The piecewise‐linear interface calculation‐based volume‐of‐fluid method is employed to track and reconstruct the ink–air interface. A geometrical computation based on Lagrangian advection is used to compute the mass flux and advance the interface. A simple and efficient model for the bubble dynamics is employed to model the effect of ink vapor on the adjacent ink liquid. To solve the surface tension‐dominated flow accurately, a hierarchical curvature‐estimation method is proposed to adapt to the local grid resolution. The numerical methods mentioned earlier have been implemented in an internal simulation code, CFD3. The numerical examples presented in the study show good performance of CFD3 in prediction of surface tension‐dominated free‐surface flows, for example, droplet ejection in thermal inkjet printing. Currently, CFD3 is used extensively for printhead development within Hewlett‐Packard. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
78.
79.
A Pronounced Halogen Effect on the Organogelation Properties of Peripherally Halogen Functionalized Poly(benzyl ether) Dendrons 下载免费PDF全文
Prof. Dr. Yu Feng Hui Chen Zhi‐Xiong Liu Yan‐Mei He Prof. Dr. Qing‐Hua Fan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(14):4980-4990
An interesting halogen‐substituent effect on the organogelation properties of poly(benzyl ether) dendrons is reported. A new class of poly(benzyl ether) dendrons with halo substituents decorating their periphery was synthesized and fully characterized. A systematic study on the gelation abilities, thermotropic behaviors, aggregated microstructures, and mechanical properties of self‐assembled organogels was performed to elucidate the halogen‐substituent effects on their organogelation propensity. It was found that the exact halogen substitutions on the periphery of dendrons exert a profound effect on the organogelation propensity, and dendrons G n ‐Cl (n=2, 3) and G2‐I proved to be highly efficient organogelators. The cooperation of multiple π–π, dispersive halogen, CH–π, and weak C?H ??? X hydrogen‐bonding interactions were found to be the key contributor to forming the self‐assembled gels. Dendritic organogels formed from G n ‐Cl (n=2, 3) in 1,2‐dichloroethane exhibited thixotropic‐responsive properties, and such thixotropic organogels are promising materials for future research and applications. 相似文献
80.